Oxygen difluoride (F 2 O) has two fluorine atoms and one oxygen atom. In the lewis structure of F 2 O, two fluorine atoms are joint with center oxygen atom. Also, there are no charges on atoms in F2O molecule. In this tutorial, you will learn how to draw the lewis structure of oxygen difluoride.Step #1: Calculate the total number of valence electrons. Here, the given ion is PO3 –. In order to draw the lewis structure of PO3 – ion, first of all you have to find the total number of valence electrons present in the PO3 – ion. (Valence electrons are the number of electrons present in the outermost shell of an atom).Step 1. The given molecule is selenium dichloride ( SeCl A 2 ). 1) On a separate sheet of paper draw the Lewis structure for Seciz (selenium dichloride) and answer the next 4 questions (Se is the central atom) How many lone pairs of electrons are on the Se atom 0.How to draw the Lewis Structure of SO3 (sulfur trioxide) - with explanationSulfur is an exception to the octet rule - it can handle up to 12 electrons!Check ...AX 2: BeH 2. 1. The central atom, beryllium, contributes two valence electrons, and each hydrogen atom contributes one. The Lewis electron structure is. 2. There are two electron groups around the central atom. We see from Figure 9.2 that the arrangement that minimizes repulsions places the groups 180° apart. 3.The -2 charge means that there are 2 extra electrons. Total: 4 + (3 × 6) + 2 = 24 electrons. The final answer MUST have this number of electrons‼! Step 2) Attach the atoms to each other using single bonds ("draw the skeleton structure") Step 3) Add electrons to all outer atoms (except H) to complete their octets.2. ) Molecule Lewis Structure. Oxygen is a diatomic molecule and contains only two oxygen atoms. In the lewis structure of O 2 molecule, a double bond is located between oxygen atoms and each oxygen atom has two lone pairs in their valence shells. There are many things to learn when we draw the O 2 lewis structure.Step #3: Put two electrons between the atoms to represent a chemical bond. Now in the above sketch of SO2F2, put the two electrons (i.e electron pair) between each atom to represent a chemical bond between them. These pairs of electrons form a chemical bond, which bonds these atoms with each other in a SO2F2 molecule.Draw the Lewis structures of these possible resonance structures, and use formal charges to predict which makes the greatest contribution to the resonance hybrid. Sulfur and oxygen form a series of 2 anions including sulfite, SO32, and sulfate, SO42. In addition to these, there are three other more complex anionsdithionite, S2O42, dithionate ...This chemistry video explains how to draw the Lewis structure of SO3 - Sulfur Trioxide. It discusses the molecular geometry, bond angle, hybridization, and ...6. (Sulfur hexafluoride) Lewis Structure. SF 6 (Sulfur hexafluoride) molecule contains one sulfur atom and six fluorine atoms. Lewis structure of SF 6 is given below. In SF 6 lewis structure, each fluorine atom has made single bonds with center sulfur atom. There are no lone pairs on sulfur atom and three lone pairs on each fluorine atom.N2O or nitrous oxide is commonly known as laughing gas. There are several other names by which this compound is known like sweet air, protoxide of nitrogen, etc. N2O is a colorless gas with a molecular weight of 44.013 g/mol. The boiling point of this compound is -88.48℃ and the melting point is -90.86℃.Steps. To properly draw the SeF 2 Lewis structure, follow these steps: #1 Draw a rough sketch of the structure. #2 Next, indicate lone pairs on the atoms. #3 Indicate formal charges on the atoms, if necessary. Let's break down each step in more detail.Lewis Structures. Page ID. A Lewis Structure is a very simplified representation of the valence shell electrons in a molecule. It is used to show how the electrons are arranged around individual atoms in a molecule. Electrons are shown as "dots" or for bonding electrons as a line between the two atoms. The goal is to obtain the "best" …A step-by-step explanation of how to draw the CHO- Lewis Dot Structure.For the CHO- structure use the periodic table to find the total number of valence elec...Steps of drawing PS3- lewis structure Step 1: Find the total valence electrons in PS3- ion. In order to find the total valence electrons in PS3- ion, first of all you should know the valence electrons present in phosphorus atom as well as sulfur atom. (Valence electrons are the electrons that are present in the outermost orbit of any atom.). Here, I'll tell you how you can easily find the ...Total valence electrons given by sulfur atom = 6. There are three oxygen atoms in SO 32- ion, Therefore. Total valence electrons given by oxygen atoms = 6 *3 = 18. There are -2 charge on SO 32- ion. Therefore there are two more electrons which contribute to the valence electrons. Total valence electrons = 6 + 18 + 2 = 26.Using Formal Charges to Distinguish Viable Lewis Structures. 9.5: Covalent Bonding- Lewis Structure. The strength of a covalent bond depends on the overlap between the valence orbitals of the bonded atoms. Bond order is the number of electron pairs that hold two atoms together. Single bonds have a ….In this video, you will learn how to draw the lewis structure for chemicals based on total valence electrons, the octet rule, duet rule, and also you will le...Lewis structure of SCl2 contains two single bonds between the Sulfur (S) atom and each Chlorine (Cl) atom. The Sulfur atom (S) is at the center and it is surrounded by 2 Chlorine atoms (Cl). The Sulfur atom has 2 lone pairs and both the Chlorine atoms have 3 lone pairs. Let's draw and understand this lewis dot structure step by step.Step #3: Put two electrons between the atoms to represent a chemical bond. Now in the above sketch of SO2F2, put the two electrons (i.e electron pair) between each atom to represent a chemical bond between them. These pairs of electrons form a chemical bond, which bonds these atoms with each other in a SO2F2 molecule.Step-by-Step Guide to Drawing NH3 Lewis Structure. 1. Count the Total Number of Valence Electrons. To begin drawing the NH3 Lewis structure, start by counting the total number of valence electrons. Valence electrons are the outermost electrons of an atom and are involved in bonding. For NH3, nitrogen (N) is in Group 5A (Group 15), so it has ...Lecture B1 Systematic Method for Creating Lewis Dot Structures. Lewis Dot Structures can be produced by following a sequence of steps. Let's produce a Lewis Dot Structure for: NH4+ (the ammonium ion). Step 1: Count valence electrons: N = 5. 4 x H = 4 x 1 = 4 "+" = -1 Total = 5+4-1= 8 electrons = 4 bonds and lone pairs.Chemistry learning made easy.This tutorial will help you deal with the lewis structure and moleculargeometry of sulfite ion (SO3 2-).What is s3 lewis structure? Verified by Proprep Tutor. Ask a tutor. If you have any additional questions, you can ask one of our experts. Ask Now.A step-by-step explanation of how to draw the SeO2 Lewis Dot Structure (Selenium dioxide).For the SeO2 structure use the periodic table to find the total num...Lewis Structure Examples. The Lewis electron dot structures of a few molecules are illustrated in this subsection. 1. Lewis Structure of CO2. The central atom of this molecule is carbon. Oxygen contains 6 valence electrons which form 2 lone pairs. Since it is bonded to only one carbon atom, it must form a double bond.this is the complete Lewis structure of CO 2. For Lewis structure purposes, the lone-pairs can only be moved from terminal atoms to the central atom to form multiple bonds, not the other way around. 7. Formal charges check: all atoms have formal charges equals to 0 in this structure. FC (C) = 4 -½× (4×2) = 0.Chemistry learning made easy.This tutorial will help you deal with the lewis structure and moleculargeometry of sulfite ion (SO3 2-).Calculate the Total Number of Valence Electrons. To create the Lewis structure, we need to determine the total number of valence electrons in SF2. Add the valence electrons of sulfur and fluorine: Sulfur (S) = 6 valence electrons. Fluorine (F) = 7 valence electrons each (2 atoms) Total valence electrons = 6 + 7*2 = 20. 2.Writing the Lewis structures for a molecule with resonance - Draw the Lewis structure for the trisulfur (S3molecule). Be sure to include all resonance struct...In the lewis structure of H 2 O, there are two single bonds around oxygen atom. Hydrogen atoms are joint to oxygen atom through single bonds. Also, there are two lone pairs on oxygen atom. Water molecule is a simple molecule. Drawing lewis structure of water molecule is simple than some of other complex molecules or ions.Place a double headed arrow <=> between the 2. There may be 3 or 4 possible structures, this is a pain, but all must be drawn. Here are more Lewis structures videos of molecules with resonance. Lewis Dot of the Chlorate Ion ClO 3-Lewis Dot of the Chlorite Ion ClO 2-Lewis Dot of Chlorine Dioxide ClO 2. Lewis Dot of the Sulfate Ion SO 4 2-Feb 27, 2023 · Writing the Lewis structures for a molecule with resonance - Draw the Lewis structure for the trisulfur (S3molecule). Be sure to include all resonance struct... An introduction to Writing the Lewis Structures for a Molecule with ResonanceShopping online can be a great way to save time and money, but it can also be a bit daunting if you’ve never done it before. John Lewis is one of the most popular online retailers ...For example CH 3 CNO can be represented by at least three different but valid Lewis structures called resonance forms, or resonance structures, shown below. However, a stable compound such as the above does not exist in multiple states represented by structures I, or II, or III. The compound exists in a single state called a hybrid of all three ...Oct 17, 2011 · I quickly take you through how to draw the Lewis Structure of SO3 2- (Sulfite Ion) . I also go over hybridization, shape and bond angles. Step-by-Step Guide to Drawing the SO3 2- Lewis Structure. 1. Count Valence Electrons. Begin by determining the total number of valence electrons in the SO3 2- ion. In this molecule, there is one sulfur (S) atom and three oxygen (O) atoms, along with the two additional electrons due to the -2 charge. Oxygen has six valence electrons, while ... You'll need to place a double bond on the Oxygen atom in order to have the best Lewis structure. When you're done put brackets, along with 2-, around the Lewis structure for SO 3 2-to show that it is an ion with a negative two charge. SO 3 2-has a total of 26 valence electrons (remember that -2 charge counts as two valence electrons). A step-by-step explanation of how to draw the SeO2 Lewis Dot Structure (Selenium dioxide).For the SeO2 structure use the periodic table to find the total num...What is the Lewis structure of [//substance:H3O+//]? Natural Language; Math Input; Extended Keyboard Examples Upload Random. Compute answers using Wolfram's breakthrough technology & knowledgebase, relied on by millions of students & professionals. For math, science, nutrition, history, geography, engineering, mathematics, linguistics, sports ...Answer link. There are seven resonance structures for "SO"_3. > When you draw the Lewis structure, you first get the three structures at the top. In each of them, "S" has a formal charge of +2 …Compute answers using Wolfram's breakthrough technology & knowledgebase, relied on by millions of students & professionals. For math, science, nutrition, history ...The notification message that Amazon S3 sends to publish an event is in the JSON format. For a general overview and instructions on configuring event notifications, see Amazon S3 Event Notifications. This example shows version 2.2 of the event notification JSON structure. Amazon S3 uses versions 2.1 , 2.2, and 2.3 of this event structure.April 2, 2024 by Deep. The information on this page is fact-checked. Lewis structure of SeS 2 | Image: Root Memory. The Lewis structure of SeS2 contains two double bonds, with selenium in the center, and two sulfurs on either side. There are two lone pairs on each sulfur atom, and one lone pair on the selenium atom.Step #1: Calculate the total number of valence electrons. Here, the given ion is PO3 –. In order to draw the lewis structure of PO3 – ion, first of all you have to find the total number of valence electrons present in the PO3 – ion. (Valence electrons are the number of electrons present in the outermost shell of an atom).The Lewis structure of SEO3 consists of one sulfur atom bonded to three oxygen atoms.; The central sulfur atom in SEO3 has a lone pair of electrons.; The Lewis structure helps in understanding the bonding and electron arrangement in a molecule.; SEO3 is a polar molecule due to the presence of a lone pair on the central atom.; …I 2 lewis structure. There is only a single bond between iodine atoms and three lone pairs on each iodine atoms. So, this lewis structure is a very simple. Steps of drawing lewis structure of I 2 molecule. When we draw a lewis structure, guidelines are given. Number of steps can be changed according the complexity of the molecule or ion.Steps of drawing PS3- lewis structure Step 1: Find the total valence electrons in PS3- ion. In order to find the total valence electrons in PS3- ion, first of all you should know the valence electrons present in phosphorus atom as well as sulfur atom. (Valence electrons are the electrons that are present in the outermost orbit of any …Molecules formed from these elements are sometimes called hypervalent molecules. Figure 7.3.4: shows the Lewis structures for two hypervalent molecules, PCl 5 and SF 6. Figure 7.3.4: In PCl 5, the central atom phosphorus shares five pairs of electrons. In SF 6, sulfur shares six pairs of electrons.Question: Draw the most important Lewis structure for [S3]2− and then answer the following questions. The underlined atom is the central atom. All other atoms are bonded directly to the central atom.Step 2: Select the central atom. For selecting the center atom, you have to remember that the atom which is less electronegative remains at the center. Now here the given molecule is SO3 (sulfur trioxide) and it contains sulfur atom (S) and oxygen atoms (O). You can see the electronegativity values of sulfur atom (S) and oxygen atom (O) in the ...Lewis structure. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures ( LEDs ) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule. [1] [2] [3] A Lewis structure can be drawn for ...You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Question: Draw the Lewis structure for the disulfur monoxide (S20) molecule. Be sure to include all resonance structures that satisfy the octet rule. alo 2 Ar. There are 2 steps to solve this one.A step-by-step explanation of how to draw the OF2 Lewis Dot Structure (Oxygen difluoride).For the OF2 structure use the periodic table to find the total numb...This problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Question: Draw the Lewis structure for the polyatomic trisulfide (S ) anion. Be sure to include all resonance structures that satisfy the octet rule. Ĉ x 87 00 5 ?A step-by-step explanation of how to draw the NO3- Lewis Dot Structure (the Nitrate ion).For the NO3 - structure use the periodic table to find the total num...Oct 20, 2020 · Resonance occurs when we can draw two or more legitimate Lewis structures for the same molecule. Resonance only occurs when a molecule has at least one double bond. Molecules with only single bonds never show resonance. Resonance structures must all have the correct number of electrons and must all obey the octet rule. Oct 11, 2023 · The Lewis dot structure for SO 32- displays a total of 26 valence electrons i.e., 13 electron pairs. Out of the 13 electron pairs, there are 4 bond pairs and 9 lone pairs. Out of the 9 lone pairs, 1 lone pair of electrons is situated on the central sulfur atom. S X 3 X 2 − \ce{S3^2-} S X 3 X 2 −. And as we can see, it only is made of sulfur. Sulfur is an element located in the sixteenth group of the periodic table, which means it has six valence electrons. It can therefore theoretically form a maximum of six bonds, and, unlike oxygen, due to its size and the availability of d d d orbitals, it does ...This chemistry video tutorial explains how to draw the lewis structure of CO3 2- also known as the carbonate ion. This video discusses the resonance structu...A step-by-step explanation of how to draw the SF3 - Lewis Dot Structure.For the SF3 - structure use the periodic table to find the total number of valence el...N2O or nitrous oxide is commonly known as laughing gas. There are several other names by which this compound is known like sweet air, protoxide of nitrogen, etc. N2O is a colorless gas with a molecular weight of 44.013 g/mol. The boiling point of this compound is -88.48℃ and the melting point is -90.86℃.6 Steps to Draw the Lewis Structure of F2 Step #1: Calculate the total number of valence electrons. Here, the given molecule is F2 (Fluorine). In order to draw the lewis structure of F2, first of all you have to find the total number of valence electrons present in the F2 molecule. (Valence electrons are the number of electrons present in the outermost shell of an atom). The structure on the right is the Lewis electron structure, or Lewis structure, for H 2 O. With two bonding pairs and two lone pairs, the oxygen atom has now completed its octet. Moreover, by sharing a bonding pair with oxygen, each hydrogen atom now has a full valence shell of two electrons. If you’re in the market for new curtains, there’s no better time to shop than during a John Lewis curtains sale. Known for their high-quality and stylish home decor, John Lewis off...Steps. By using the following steps, you can easily draw the SF 3 + Lewis structure. #1 Draw skeleton #2 Show chemical bond #3 Mark lone pairs #4 Calculate formal charge and check stability (if octet is already completed on central atom). Let’s one by one discuss each step in detail.The Lewis dot structure of a molecule is referred to as a simplified representation of all the valence electrons present in it. Therefore, the very first step while drawing the Lewis structure of SO 3 2 – is to count the total valence electrons present in the concerned elemental atoms.. There are two different elemental atoms present in the …2. Draw the Lewis electron dot diagram for silicon. Extend. We know that water can be broken down into elemental hydrogen and elemental oxygen, and that the ratio of these gases that form is 2:1. Since both of these gases are diatomic (H 2 and O 2), water is made of H and O atoms in a 2:1 ratio as well. The observable properties of water ...VSEPR 3D Structures of Molecules. VSEPR 3D Structures of Molecules. Lewis structures are a good representation of the structure of a molecule in 2 dimensions. To visualize the structure of a molecule in 3 dimensions however, we need to introduce a model known as the valence-shell electron-pair repulsion (VSEPR) theory.Figure 11.3a: Lewis structure of calcium atom (credit: Chemistry (OpenStax), CC BY 4.0 ). Lewis symbols illustrate the number of valence electrons for each element in the third period of the periodic table as shown in Figure 11.3b. Figure 11.3c shows the Lewis symbols for the first twenty elements of the periodic table.this is the complete Lewis structure of CO 2. For Lewis structure purposes, the lone-pairs can only be moved from terminal atoms to the central atom to form multiple bonds, not the other way around. 7. Formal charges check: all atoms have formal charges equals to 0 in this structure. FC (C) = 4 -½× (4×2) = 0.If you’re in the market for a new or used car in Hays, KS, chances are you’ve come across Lewis Ford Toyota. With a reputation for quality vehicles and exceptional customer service...Question: Question 8 (1 point) Draw the Lewis Structure of Sis32-(OR SI S3 2 minus). How many lone pairs are present? 0 1 2 5 6 6 7 Question 10 (1 point) Saved Draw ...An aluminum atom (a metal) has three electrons in its valence (outer) shell to give away.Sulfur atoms (non-metals) have six electrons in their outer shells, ...A step-by-step explanation of how to draw the SeO2 Lewis Dot Structure (Selenium dioxide).For the SeO2 structure use the periodic table to find the total num...Step-by-Step Guide to Drawing NH3 Lewis Structure. 1. Count the Total Number of Valence Electrons. To begin drawing the NH3 Lewis structure, start by counting the total number of valence electrons. Valence electrons are the outermost electrons of an atom and are involved in bonding. For NH3, nitrogen (N) is in Group 5A (Group 15), so it has ...2. Each hydrogen atom (group 1) has one valence electron, carbon (group 14) has 4 valence electrons, and oxygen (group 16) has 6 valence electrons, for a total of [ (2) (1) + 4 + 6] = 12 valence electrons. 3. Placing a bonding pair of electrons between each pair of bonded atoms gives the following: Six electrons are used, and 6 are left over.The Lewis structures, also called Lewis-dot diagrams or electron dot diagrams or Lewis dot structure are pictures that show the bonding between a pair of electrons and the atoms of a molecule . Each dot represents one electron. Two dots side by side represent a lone pair of electrons.Step 3: Determine the Number of Bonds in the Molecule. Covalent bonds are formed when one electron from each atom forms an electron pair. Step 2 tells how many electrons are needed and Step 1 is how many electrons you have. Subtracting the number in Step 1 from the number in Step 2 gives you the number of electrons needed to complete the octets ...Nov 27, 2022 · S2O is a chemical formula for disulphur monoxide. And to help you understand the Lewis Structure of this molecule, we are going to share our step-by-step met... The information on this page is fact-checked. Lewis structure of NH 2- | Image: Root Memory. The Lewis structure of NH2- contains two single bonds, with nitrogen in the center, and two hydrogens on either side. There are two lone pairs on the nitrogen atom, and the hydrogen atom does not have any lone pair. Plus, there is a negative (-1 ...Trisulfide(2-) | S3-2 | CID 5460599 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. ... [S3](2-) DTXSID10920149; KBMBVTRWEAAZEY-UHFFFAOYSA-L [SSS](2-) Q27110043; PubChem. 3 Chemical and Physical Properties. 3 ...Oct 29, 2021 · The -2 charge means that there are 2 extra electrons. Total: 4 + (3 × 6) + 2 = 24 electrons. The final answer MUST have this number of electrons‼! Step 2) Attach the atoms to each other using single bonds (“draw the skeleton structure”) Step 3) Add electrons to all outer atoms (except H) to complete their octets.
A step-by-step explanation of how to draw the NCl3 Lewis Dot Structure (Nitrogen trichloride).For the NCl3 structure use the periodic table to find the total.... Dekalb county georgia trash pickup schedule
Structure, properties, spectra, suppliers and links for: trisulfur.Aug 17, 2020 · The objective here is to draw the Lewis structure for the polyatomic trisulfide anion and to be sure all resonance structures that satisfy the octet rule are included. The Lewis structure for Polyatomic trisulfide anion. The first step is to the layout the skeleton of the Polyatomic trisulfide anion. S S S How is the Lewis structure for S3 molecule depicted? Verified solution by a Proprep tutor. Related Videos. General Chemistry All. 0% completed. Lewis Theory of Chemical Bonding. General Chemistry All. 0% completed. Lewis Theory of Chemical Bonding. Ask a tutor. If you have any additional questions, you can ask one of our experts.2. ) Molecule Lewis Structure. Oxygen is a diatomic molecule and contains only two oxygen atoms. In the lewis structure of O 2 molecule, a double bond is located between oxygen atoms and each oxygen atom has two lone pairs in their valence shells. There are many things to learn when we draw the O 2 lewis structure.Lewis structure: diagram showing lone pairs and bonding pairs of electrons in a molecule or an ion. Lewis symbol: symbol for an element or monatomic ion that uses a dot to represent each valence electron in the element or ion. lone pair: two (a pair of) valence electrons that are not used to form a covalent bond.Recognize that you are drawing the Lewis structure for SO3, which consists of one sulfur (S) atom and three oxygen (O) atoms. Sulfur has 6 valence electrons, and each oxygen has 6 valence electrons. Calculate the total number of valence electrons: 6 (S) + 6 (O) * 3 = 24 valence electrons. 2. Place the Least Electronegative Atom in the Center.1.2.3 Guidelines about Formal Charges in Lewis Structures. The purpose of formal charges is to compare the difference between the number of valence electrons in the free atom and the number of electrons the atom "owns" when it is bonded. The smaller the difference, the "happier" (more stable) the atom is. The atom owns all of the lone pair (non-bonding) electrons and half of the ...An introduction to Writing the Lewis Structures for a Molecule with ResonanceThis problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Question: Draw the Lewis dot structure for S2−. Show the formal charges of all atoms in the correct structure. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom.SO42- Lewis Structure, Hybridization, Bond Angle and Molecular Geometry. SO42- is a chemical name for the sulfate ion. It comprises one Sulphur atom, four Oxygen atoms, and a charge of -2. It is a polyatomic anion and is used widely to synthesize other sulfates such as Zinc Sulfates, Magnesium sulfates, Iron sulfates, and much more.6 Steps to Draw the Lewis Structure of O3 Step #1: Calculate the total number of valence electrons. Here, the given molecule is O3 (ozone). In order to draw the lewis structure of O3, first of all you have to find the total number of valence electrons present in the O3 molecule. (Valence electrons are the number of electrons present in the outermost shell of an atom).The Lewis dot structure of a molecule is referred to as a simplified representation of all the valence electrons present in it. Therefore, the very first step while drawing the Lewis structure of SO 3 2 - is to count the total valence electrons present in the concerned elemental atoms.. There are two different elemental atoms present in the sulfite [SO 3] 2-ion, i.e., sulfur (S) atom and ...6 Steps to Draw the Lewis Structure of CO3 2-Step #1: Calculate the total number of valence electrons. Here, the given ion is CO3 2- ion. In order to draw the lewis structure of CO3 2- ion, first of all you have to find the total number of valence electrons present in the CO3 2- ion. (Valence electrons are the number of electrons present in the ….
Popular Topics
- Can you see if someone deleted a message on discordCraigslist west coast
- Best build ds2Farmers market inverness fl
- FlashthemesJimmy john's fayetteville ga
- Ciox edeliveryMy walmart order was cancelled
- Lisa sparks iu healthJames borling salas
- Howard miller clocks partsFirst cash pawn hazelwood
- Rancho alegre san bernardino menuPueblo blood donation